Effect of Rotating Electrode
نویسندگان
چکیده
A gold coated copper rotating electrode was used to eliminate surface oxidation effect. This study examined the effect of electrode rotation on the ozone generation process and showed that an ozonizer with an electrode rotating system might be a possible way to increase ozone-synthesis efficiency. Two new phenomena appeared during experiments with the rotating electrode. First was that ozone concentration increased to about two times higher than that of the case with no rotation. Second, input power and discharge area were found to increase with the rotation speed. Both ozone concentration and ozone production efficiency improved in the case of rotating electrode compared to the case with a non-rotating electrode. One possible reason for this was the increase in discharge length of micro-discharges during electrode rotation. The rotating electrode decreased onset voltage, while reactor capacitance increased with rotation. Use of a rotating-type electrode allowed earlier observation of the ozone zero phenomena compared with a non-rotating electrode because, during rotation, the entire electrode surface was functional, allowing nitrogen on the electrode surface to be evenly consumed. Nitrogen demand increased with increasing rotation speed. Keywords—Rotating electrode, input power, onset voltage, discharge canal.
منابع مشابه
RATE CONSTANTS FUR THE ELECTRODE REACTIONS OF QUINONES IN CHLOROFORM: THE DEPENDENCE ON ELECTRODE MAmRIAL,S AND APPARENT STANDARD POENTIALS
The reduction process for some quinones has been studid by cyclic voltammeby, rotating disk electrode voltammetry and chronopotentiometry in chloroform at platinum, gold and glassy carbon electrodes using tetrabutylmonium perchlorate (TB AP) as supporting eiectrolyte. The results obtained from this study reveal that the reduction of the quinones is two one-electron processes, the first redu...
متن کاملEffect of Magnetic Field on the Rotating Flow in a Similar Czochralski Configuration
We present a numerical study of the rotating flow generated by two rotating disks in co-/counter-rotating, inside a fixed cylindrical enclosure similar to the Czochralski configuration (Cz). The enclosure having an aspect ratio A = H/Rc equal to 2, filled with a low Prandtl number fluid (Pr = 0.011), which is submitted to a vertical temperature gradient. The finite volume method has been used ...
متن کاملNatural Frequency of Rotating Single-Walled Carbon Nanotubes with Considering Gyroscopic Effect
This paper investigates the bending vibration of rotating single-walled carbon nanotubes (SWCNTs) based on nonlocal theory. To this end, the rotating SWCNTs system modeled as a beam with a circular cross section and the Euler-Bernoulli beam theory (EBT) is applied with added effects such as rotary inertia, gyroscopic effect and rotor mass unbalance. Using nonlocal theory, two coupled sixth orde...
متن کاملDevelopment of rotating liquid membrane disk electrode and rotating liquid membrane ring-liquid membrane disk electrode and evaluation of characteristics of ion transfer reactions at the rotating aqueous/organic solution interface.
A liquid membrane disk electrode, LMDE, and a liquid membrane ring-liquid membrane disk electrode, LMRE-LMDE, were developed by placing a gelled polyvinyl chloride thin membrane impregnated with 2-nitrophenyl octyl ether, NPOE-LM, on the surface of a glassy carbon, GC, disk or ring electrode. The voltammogram for the ion transfer at the interface between an aqueous solution, W, and NPOE-LM was ...
متن کاملReaction/Diffusion at Electrode/Solution Interfaces: The EC2 Reaction
A closed form analytical expression is derived for the normalized current versus potential response expected for a rotating disc electrode in which an initial fast electron transfer reaction is followed by a homogeneous electrochemical reaction which exhibits second order kinetics. The effect of the homogeneous reaction on the shape of the voltammetric response curve is calculated.
متن کامل